Short answer: no.

Longer answer: iCloud Keychain is end-to-end encrypted credential storage, and its workflow is:

Need password -> Secure system hook to Keychain -> Keychain requests unlock via (face/finger/passphrase as appropriate) -> Password decrypted and auto filled.

There are also third-party options, which can nominally use NFC keys[0] as auth factors, but I’m not currently aware of any that actually do.

Personally, I use 1Password, because I’ve still got a Windows box in my world, and need something cross-platform, and since I’m paying for it, I know it’s the product and not me.

[0] https://developer.apple.com/documentation/authenticationserv...

The OPs workflow is entirely possible with https://github.com/mssun/passforios since over a year ago.