Are there any other CAs that support ACME?

Is ACME an Internet standard yet?

Is that turning into monoculture?

ACME is currently an IETF draft: https://tools.ietf.org/html/draft-ietf-acme-acme-07

As far as I know there's only one serious server-side implementation right now, and that's Let's Encrypt's open-source Boulder project: https://github.com/letsencrypt/boulder